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Monday, August 24 • 3:40pm - 4:00pm
[0140] The simple and versatile synthesis of tetrasubstituted pyrroles and subsequent functionalization

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The cycloaddition–retroelectrocyclization reaction is a useful reaction for the conversion of electron-rich alkynes and electron-poor alkenes into buta-1,3-dienes.1 We have recently shown that this reaction is more widely applicable to ester-substituted alkenes to afford compounds of type 1.2 In this presentation we will describe how compounds of type 1 can be efficiently and rapidly converted into highly substituted pyrroles 2. Further one-step functionalization allows isolation of substituted pyrroles of type 3 and, 4 and 2H-pyrrol-2-ones 5, the latter of which exhibit strong chromophoric behaviour and a bathochromic shift upon protonation

ST Lecturers

Monday August 24, 2015 3:40pm - 4:00pm
UCEN Lobero