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Monday, August 24 • 4:00pm - 4:20pm
[0147] One-pot Synthesis of cyclic analogues of hexamethylenebis(3-pyridine)amide (HMBPA

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A series of cyclic analogues of hexamethylenebis(3-pyridine)amide was prepared based upon a Ugi-3CR and aza-Diels-Alder reaction as a post-functionalization in a one-pot process. A simple condensations of commercially available diamine and aldehydes followed by isonitrile -addition provides the oxazoles intermediates, finally an aza-Diels-Alder cycloaddition and ring-opening using maleic anhydride provides the desired compounds in modest overall yield (12 examples, 6-69%) in approximately 40 min using microwaves as the heat source and scandium (III) triflate as a catalyst.

ST Lecturers
avatar for Eduardo González-Zamora

Eduardo González-Zamora

Full Professor, Universidad Autónoma Metropolitana
ProfessorUniversidad Autónoma Metropolitana

Monday August 24, 2015 4:00pm - 4:20pm PDT
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